Structural characterization of the μ-nitrido complex {[Fe(OEP)]2N}
نویسندگان
چکیده
منابع مشابه
Synthesis and characterization of μ-nitrido, μ-carbido and μ-oxo dimers of iron octapropylporphyrazine.
Three μ-X bridged diiron octapropylporphyrazine complexes having Fe(III)-O-Fe(III), Fe(+3.5)-N[double bond, length as m-dash]Fe(+3.5) and Fe(IV)[double bond, length as m-dash]C[double bond, length as m-dash]Fe(IV) structural units have been prepared and characterized by UV-vis, EPR, X-ray absorption spectroscopy and electrochemical methods. Single crystals of all the complexes were obtained fro...
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Intramolecular activation processes of vulnerable ligand C-H bonds frequently limit the thermal stability and accessibility of late transition metal complexes with terminal metal nitrido units. In this study chloro substitution of the 2,6-ketimine N-aryl substituents (2,6-C(6)H(3)R(2), R = Cl) of the pyridine, diimine ligand is probed to increase the stability of square-planar iridium nitrido c...
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Nickel(II) complex of [NiL2](ClO4)2, where L is an unsymmetrical tridentate ligand of 2-(2-aminoethyl)imino-3-butanone oximehas been synthesized by a template condensation reaction. The complex was characterized on the basis of microanalytical, spectroscopic, and other physicochemical properties. X-ray diffraction study of the complex revea...
متن کاملSyntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes.
The syntheses and X-ray crystal structures of dinuclear μ-azido and μ-nitrido bridged iridium complexes bearing the pyridine, diimine ligand (PDI) are reported. Their electronic structures and formal oxidation states of the metal centers are analyzed by theoretical and experimental methods, revealing the non-innocence of the PDI and nitrido ligands.
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ژورنال
عنوان ژورنال: Journal of Porphyrins and Phthalocyanines
سال: 2014
ISSN: 1088-4246,1099-1409
DOI: 10.1142/s1088424614500096